Sinopec EP 0 Grease Material Safety Data Sheet (MSDS)

Identification

Product Name: Sinopec EP 0 Grease
Synonyms: Extreme Pressure Lithium Grease 0
Manufacturer: China Petroleum & Chemical Corporation (Sinopec)
Recommended Use: Lubrication of industrial and automotive machinery under heavy load
Contact Information: Sinopec Safety and Compliance Office, No.6A, Huapichang Hutong, Xicheng District, Beijing, P.R. China
Emergency Contact Number: +86-10-59960114
Product Code: Commercial blend, bulk and cartridge packaging

Hazard Identification

GHS Classification: Not classified as hazardous according to GHS
Potential Health Effects: Skin and eye contact can cause mild irritation; ingestion and inhalation exposure may lead to discomfort; high-pressure injection injuries possible
Label Elements: No pictogram or signal word required
Precautionary Statements: Wash thoroughly after handling; avoid direct contact with eyes and skin; do not ingest
Routes of Exposure: Skin contact, eye contact, inhalation of mists during application, incidental ingestion
Long-Term Effects: Prolonged or repeated skin exposure can cause dermatitis or oil acne
Other Hazards: Slippery when spilled; high-pressure application equipment can inject grease into skin

Composition / Information on Ingredients

Base Oil: Highly refined mineral oil, 60–90% by weight (CAS No. 64742-54-7)
Thickener: Lithium Hydroxystearate, 5–20% (CAS No. 7620-77-1)
Additives: Extreme pressure additives (zinc dialkyldithiophosphate, 0–5%), anti-oxidants, corrosion inhibitors
Other Ingredients: Proprietary formulation as per Sinopec process; trace contaminants below reportable thresholds

First Aid Measures

Eye Contact: Rinse cautiously with water for several minutes; remove contact lenses if present and easy to do; keep flushing if irritation persists; seek medical attention for continued discomfort
Skin Contact: Wipe excess from skin and wash with soap and water; remove contaminated clothing and wash before reuse; seek medical advice if irritation or rash develops
Inhalation: Move individual to fresh air; administer oxygen if breathing is difficult; get medical support if symptoms do not resolve
Ingestion: Rinse mouth; seek medical attention; do not induce vomiting unless directed by medical staff
High-Pressure Injection:** Immediate emergency surgery required; treat as medical emergency

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, foam, carbon dioxide, or sand for larger quantities
Unsuitable Methods: Direct water stream may scatter burning material
Specific Hazards: Incomplete combustion releases carbon monoxide, carbon dioxide, sulfur oxides, and possibly metal fumes
Protective Equipment for Firefighters: Full protective clothing and self-contained breathing apparatus
Fire Precautions: Move containers from fire area if safe; cool containers exposed to flames with water spray
Special Instructions: Evacuate personnel from area; prevent contaminated run-off from entering drains

Accidental Release Measures

Personal Precautions: Use chemical-resistant gloves, eye protection, long sleeves; ensure adequate ventilation
Environmental Precautions: Contain spill and prevent entry into soil, waterways, storm drains, or sewers
Clean-Up Methods: Shovel or scrape up grease and place in approved waste container; clean floor with degreasing agent; dispose of according to regulations
Slippery Surface Warning: Area will be slippery; wash residue with detergent and water
Large Release: Contact local environmental authorities for procedures; barricade area; avoid contamination to natural habitats

Handling and Storage

Handling Precautions: Avoid prolonged or repeated skin contact; practice good hygiene; do not eat, drink, or smoke during use; use with adequate ventilation
Container Handling: Keep containers tightly closed; open slowly to release any pressure; keep outside of drums free from residue
Storage Conditions: Store in cool, dry, well-ventilated area away from direct sunlight and heat, separate from oxidizers
Storage Temperature: Recommended 5–40°C (41–104°F); do not freeze
Safe Incompatibilities: Avoid strong acids, bases, and oxidizing agents
Packaging Materials: Use original containers or compatible oil-resistant materials

Exposure Controls and Personal Protection

Exposure Limits: Mineral oil mist OSHA PEL: 5 mg/m³ (8 hr TWA); ACGIH TLV: 5 mg/m³
Engineering Controls: Adequate general and local exhaust ventilation in work area
Personal Protection: Safety glasses, gloves (nitrile, neoprene), protective clothing
Respiratory Protection: Required only if mist or vapor generated above control limits
Hygiene Measures: Wash hands before eating or drinking; prevent contact with skin and eyes; do not wear contaminated clothing home
Environmental Protection: Prevent spills from reaching water; follow local emission limits

Physical and Chemical Properties

Appearance: Smooth, buttery, pale to medium brown grease
Odor: Characteristic mild petroleum odor
Odor Threshold: No data available
pH: Not applicable (insoluble)
Melting Point/Freezing Point: ~180°C (dropping point, ASTM D566)
Boiling Point: Not applicable
Flash Point: >200°C (base oil)
Evaporation Rate: Negligible
Flammability: Not classified as flammable; will burn if exposed to full flame
Vapor Pressure: <0.01 mmHg at 20°C (base oil)
Vapor Density: Heavier than air
Solubility: Insoluble in water; soluble in hydrocarbon solvents
Partition Coefficient (n-octanol/water): Not established
Autoignition Temperature: >300°C
Decomposition Temperature: No data
Viscosity: ~80 cSt at 40°C (base oil)
Other Information: NLGI grade: 0; worked penetration: 355–385 (ASTM D217); slightly tacky

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions; no hazardous polymerization
Reactivity: Non-reactive under normal handling and storage
Potentially Hazardous Reactions: Can react with strong oxidizers, acids, or alkalis
Conditions to Avoid: Excessive heat, open flame, long exposure to air
Hazardous Decomposition Products: Smoke, carbon oxides, sulfur oxides, metal compounds
Incompatible Materials: Strong oxidizing agents, sources of ignition

Toxicological Information

Acute Toxicity: Expected to have low acute toxicity based on ingredient profile
Skin Corrosion/Irritation: May cause mild and reversible irritation; repeated exposure may cause dryness, cracking, or dermatitis
Eye Damage/Irritation: Can cause short-term discomfort, redness, or tearing
Respiratory Sensitization: Not expected for normal conditions
Ingestion: Not considered toxic; small amounts unlikely to cause acute health effects, but ingestion of large quantities may result in gastrointestinal upset
Aspiration Hazard: Risk if lubricant enters lungs during ingestion or vomiting
Chronic Effects: Prolonged, repeated exposure may lead to skin sensitization or more severe reactions
Carcinogenicity: No components listed as carcinogenic by IARC, OSHA, or NTP
Mutagenicity and Reproductive Toxicity: Not expected; no ingredients known to impair fertility or cause genetic defects

Ecological Information

Ecotoxicity: Harmful to aquatic life with long lasting effects if released in large amounts; mineral oil can cause film on water impairing oxygen transfer
Persistence and Degradability: Mineral oil is inherently biodegradable at a slow rate; additives and thickeners persist longer
Bioaccumulation Potential: Not expected to bioaccumulate significantly based on viscosity and limited solubility
Mobility in Soil: Low mobility in soil; binds to particulates
Other Adverse Effects: Grease can clog soil and aquatic systems if not contained
Preventative Measures: Keep product out of drains and natural waters; clean up spills promptly and follow local regulations

Disposal Considerations

Waste Disposal: Dispose according to local, regional, and national regulations; state and municipal rules may vary
Methods: Do not discharge to sewers or surface waters; recycle or dispose at licensed waste oil facility
Container Disposal: Empty containers retain residue; do not reuse for other purposes; triple rinse and recycle where possible
Special Precautions: Avoid contamination of food, animal feed, or drinking water

Transport Information

UN Number: Not regulated for land, sea, or air transport
Proper Shipping Name: Not classified as hazardous for transport
Hazard Class: Not subject to transport regulations
Packing Group: Not applicable
Label Requirements: No special markings on containers for transport
Emergency Response Guide Number: Not assigned
Special Precautions for User: Protect containers from physical damage; prevent spillage during loading and unloading

Regulatory Information

EU Regulations: Not classified as hazardous according to Regulation (EC) No 1272/2008 (CLP); ingredients not on the Candidate List of SVHCs
US Regulations: All components listed on TSCA inventory; not subject to SARA Title III, Section 313 reporting
International Inventories: Components listed on Canada DSL/NDSL, EU EINECS/ELINCS, Australia AICS, and other national inventories
Other Regulations: Compliant with China GB/T 501 standard for lubricating greases; not regulated under UN Model Regulations
Product Safety: Hazard communication training recommended for workers; review national occupational exposure standards regularly