Sinopec Engine Oil Material Safety Data Sheet (MSDS)

Identification

Product Name: Sinopec Engine Oil
Recommended Use: Lubrication of internal combustion engines
Manufacturer: China Petroleum & Chemical Corporation (Sinopec)
Address: 22 Chaoyangmen North Street, Chaoyang District, Beijing, China
Emergency Contact Number: +86-10-59960114
Product Codes: Varies based on viscosity grade and formulation

Hazard Identification

Classification: Not classified as hazardous under GHS criteria
Main Hazards: Prolonged or repeated skin contact may cause irritation or dermatitis; inhalation of mists can irritate the respiratory tract; heated oil can cause burns
NFPA Ratings (scale 0-4): Health: 1, Flammability: 1, Reactivity: 0
Other Hazards: Slippery when spilled, toxic to aquatic life with long lasting effects

Composition / Information on Ingredients

Base Oil: Severely refined mineral oils, typically 70-95% by weight
Additives: Proprietary performance additives, zinc dialkyldithiophosphate (ZDDP) 0.5-2%, detergents < 2%, pour point depressants < 1%, antifoam agents < 0.1%
Chemical Identity: Mixture, exact composition considered trade secret
CAS Numbers: Base Oil (64742-54-7), ZDDP (68649-42-3), Polyisobutylene (9003-27-4)

First Aid Measures

Inhalation: Remove to fresh air, provide oxygen if breathing is difficult, seek medical attention for persistent symptoms
Skin Contact: Wash thoroughly with soap and water, remove contaminated clothing, use moisturizer if irritation occurs
Eye Contact: Rinse immediately with plenty of water for at least 15 minutes, seek medical advice if irritation remains
Ingestion: Do not induce vomiting, rinse mouth, seek immediate medical attention, never give anything by mouth to an unconscious person

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry chemical, carbon dioxide, water spray (avoid direct stream, as it may spread fire)
Unsuitable Extinguishing Media: Straight stream of water
Hazards from Combustion: May produce thick smoke, carbon monoxide, sulfur oxides, aldehydes, phosphorus oxides during combustion
Protective Equipment: Firefighters should wear full protective gear including SCBA, keep containers cool by spraying with water

Accidental Release Measures

Personal Precautions: Wear appropriate personal protective equipment, avoid skin and eye contact, prevent inhalation of mists
Environmental Precautions: Prevent entry into sewers, waterways, soil; report significant spills to local authorities
Containment: Stop leak if it can be done safely, use earth, sand, or other absorbent material to contain
Cleanup Methods: Absorb with inert material and place in suitable containers for disposal, clean residual with detergent and water

Handling and Storage

Precautions for Safe Handling: Avoid prolonged or repeated contact with skin and eyes, use in well-ventilated areas, do not get in eyes
Advice on Storage: Store in tightly closed, properly labeled containers in a cool, dry, well-ventilated place away from heat or ignition sources
Incompatible Materials: Strong oxidizers such as chlorine, sodium hypochlorite, peroxides
Special Precautions: Prevent static discharge, use grounded equipment, keep container tightly closed when not in use

Exposure Controls and Personal Protection

Exposure Limits: Mineral oil mist: ACGIH TLV 5 mg/m³ (inhalable fraction), OSHA PEL 5 mg/m³
Engineering Controls: Local exhaust ventilation or other engineering controls to maintain airborne levels below recommended limits
Personal Protective Equipment: Nitrile or neoprene gloves, safety glasses with side shields, long-sleeved clothing, suitable respirator if exposure limits are exceeded
Hygiene Measures: Wash hands after handling; no eating, drinking, or smoking in work area; launder contaminated clothing before reuse

Physical and Chemical Properties

Appearance: Amber to brown liquid
Odor: Mild petroleum
Boiling Point: >300°C (572°F)
Melting/Pour Point: -36°C to -9°C
Flash Point: >200°C (392°F) (COC)
Autoignition Temperature: ~343°C (649°F)
Vapor Pressure: <0.01 kPa @ 20°C
Density: ~0.86-0.89 g/cm³ @ 15°C
Solubility: Insoluble in water
Viscosity: 9-16 mm²/s @ 100°C, grade dependent
Evaporation Rate: Negligible under normal conditions

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions
Conditions to Avoid: Excessive heat, open flame, ignition sources, shock, static discharge
Incompatible Materials: Strong oxidizing agents and acids
Hazardous Decomposition: Carbon monoxide, carbon dioxide, sulfur oxides, smoke; incomplete combustion may produce hazardous fumes
Polymerization: Will not occur under normal conditions

Toxicological Information

Likely Routes of Exposure: Skin, inhalation, eye, ingestion
Acute Toxicity: LD50 (oral, rats) >5,000 mg/kg; may cause mild skin or eye irritation
Chronic Effects: Prolonged or repeated skin contact can cause dermatitis; used oils may pose higher health risks
Carcinogenicity: Base oils are severely refined to remove carcinogenic components; used engine oils may contain carcinogens
Sensitization: Not expected to cause respiratory or skin sensitization
Mutagenicity/Teratogenicity: No evidence found in animal studies

Ecological Information

Ecotoxicity: Harmful to aquatic life with long lasting effects; hydrocarbon components can persist and bioaccumulate
Persistence and Degradability: Components have moderate to low biodegradability, persist in environment
Bioaccumulation Potential: Bioaccumulative based on physical and chemical properties of mineral oils and additives
Mobility in Soil: Low; binds to soil and sediments
Other Adverse Effects: Spilled oil can form a film on water surface reducing oxygen transfer and harming wildlife

Disposal Considerations

Disposal Methods: Treat as hazardous waste, recycle used oil whenever possible, dispose in accordance with local, state, and federal regulations
Contaminated Packaging: Empty containers retain residue; do not reuse; dispose according to official requirements
Special Considerations: Do not pour into drains, sewers, soil or waterways; prevent environmental contamination and follow guidance from environmental authorities

Transport Information

UN Number: Not regulated for transport in most countries
Proper Shipping Name: Not applicable for engine oil based on current guidelines
Hazard Class: Not classified
Packing Group: Not applicable
Marine Pollutant: May be considered marine pollutant if spilled in large quantities
Special Precautions for Transport: Secure containers to prevent leaks and spills, keep away from heat and direct sunlight

Regulatory Information

Labeling Requirements: Standard chemical safety symbols for mineral oil products
Inventory Status: All ingredients are listed on major chemical inventories (TSCA, DSL, IECSC, EINECS, etc.)
OSHA Hazard Communication: This material is not considered hazardous in normal conditions
Other Regulations: Complies with relevant industry, safety, and environmental regulations in countries of distribution
Right-to-Know Components: Base oils, ZDDP, detergents may be subject to right-to-know reporting in some regions
SARA Title III: Not reportable as an extremely hazardous substance
Waste Classification: Classified as used oil after service life; may become hazardous depending on contaminants